Combustion within Porous Waste

Flammable gases (primarily hydrogen and nitrous oxide but also ammonia and methane) are continuously being generated within the waste contained in the tank farms at Hanford Site. Some portions of the waste are porous and conceivably, a combustion event could occur within the waste due to accidental ignition. This has been postulated as a potential hazard since deflagrations and detonations are observed in laboratory experiments to propagate through combustible gases in porous materials, or through interconnected flammable gas voids. The waste in Hanford storage tanks are mainly in three different forms, a: salt cake, b: sludge, c: supernatant. Formation of a crust layer on the top of the waste is also observed in some tanks. The salt cake waste and crust resemble porous materials while sludge and supernatant looks like highly viscous fluids retaining flammable gas as bubbles or inclusions. Although laboratory experiments showed the possibility of propagation of deflagration or detonation in waste-like porous materials filled by flammable gases, the relevance of this issue to safety evaluations at Hanford is a matter of contention. In order to clarify this issue, we have reviewed the relevant data on laboratory experiments related to combustion in porous material. in doing this, we have concentrated on the flame literature rather than the detonation literature, since Makris et al. (1995) have already examined that. Further, significant mechanisms for the initiation of detonation (i.e., geometries resulting in strong flame acceleration within the dome) have not been identified therefore making flames a much more likely outcome of accidental ignition than detonation. ignition of flammable waste gases in the waste or the dome space of a tank can occur during intrusive operations into the waste or dome. External events which are not foreseeable such as lightning can also ignite the flammable gas retained in the waste. The present report only examines the basic issues in propagation of deflagration or detonation within waste. The process or probability of combustion ignition and other combustion events such as burns in the dome are not considered. After our review of the literature, some simple estimates of the potential for flame and detonation propagation are given. We conclude with a discussion of the uncertainties and measurements required to resolve this issue

Exploring the Nature of Weak Chandra Sources near the Galactic Centre

We present results from the first near-IR imaging of the weak X-ray sources discovered in the Chandra/ACIS-I survey (Wang et al. 2002) towards the Galactic Centre (GC). These ~800 discrete sources, which contribute significantly to the GC X-ray emission, represent an important and previously unknown population within the Galaxy. From our VLT observations we will identify likely IR counterparts to a sample of the hardest sources, which are most likely X-ray binaries. With these data we can place constraints on the nature of the discrete weak X-ray source population of the GC.Comment: In Proc. of ``Interacting Binaries: Accretion, Evolution, and Outcomes'', eds. L. A. Antonelli et al., AIP, Cefalu, Sicily, 200

Models of Ultraluminous X-Ray Sources with Intermediate-Mass Black Holes

We have computed models for ultraluminous X-ray sources ("ULXs") consisting of a black-hole accretor of intermediate mass ("IMBH"; e.g., ~1000 Msun) and a captured donor star. For each of four different sets of initial donor masses and orbital separations, we computed 30,000 binary evolution models using a full Henyey stellar evolution code. To our knowledge this is the first time that a population of X-ray binaries this large has been carried out with other than approximation methods, and it serves to demonstrate the feasibility of this approach to large-scale population studies of mass-transfer binaries. In the present study, we find that in order to have a plausible efficiency for producing active ULX systems with IMBHs having luminosities > 10^{40} ergs/sec, there are two basic requirements for the capture of companion/donor stars. First, the donor stars should be massive, i.e., > 8 Msun. Second, the initial orbital separations, after circularization, should be close, i.e., < 6-30 times the radius of the donor star when on the main sequence. Even under these optimistic conditions, we show that the production rate of IMBH-ULX systems may fall short of the observed values by factors of 10-100.Comment: 5 pages, 2 figures, submitted to Ap

Detonation Cell Width Measurements for H2–N2O–N2–O2–CH4–NH3 Mixtures

Detonations of mixtures containing hydrogen and nitrous oxide were investigated in the GALCIT detonation tube (280 mm diameter, 7.3 m long). The facility and previous related studies are described in Akbar et al. (1997). We measured the detonation cell width, velocity and pressure for a range of equivalence ratios in three mixtures: 1) hydrogen-nitrous oxide; 2) hydrogen-nitrous oxide with 30% nitrogen dilution; 3) hydrogen-nitrous oxide with 30% nitrogen dilution further diluted 50% by air. In addition, we investigated the influence of adding 3% methane or 3% ammonia on the detonation behavior to hydrogen-nitrous oxide mixtures. Tests were conducted at initial pressures and temperatures of 70.9 kPa and 295 K, respectively. One-dimensional, steady, (ZND model) reaction zone calculations were performed with the modified Miller and Bowman hydrogen-nitrous oxide-methane-ammonia-oxygen-nitrogen mechanism (Akbar et al. 1997). These calculations were used to correlate and extrapolate the measured cell widths and also to determine the effect of initial conditions on the cell width

Are team personality and climate related to satisfaction and software quality? Aggregating results from a twice replicated experiment

This is the author’s version of a work that was accepted for publication in Information and Software Technology. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Information and Software Technology, [VOL 57, (2015)] DOI 10.1016/j.infsof.2014.09.002Context Research into software engineering teams focuses on human and social team factors. Social psychology deals with the study of team formation and has found that personality factors and group processes such as team climate are related to team effectiveness. However, there are only a handful of empirical studies dealing with personality and team climate and their relationship to software development team effectiveness. Objective We present aggregate results of a twice replicated quasi-experiment that evaluates the relationships between personality, team climate, product quality and satisfaction in software development teams. Method Our experimental study measures the personalities of team members based on the Big Five personality traits (openness, conscientiousness, extraversion, agreeableness, neuroticism) and team climate factors (participative safety, support for innovation, team vision and task orientation) preferences and perceptions. We aggregate the results of the three studies through a meta-analysis of correlations. The study was conducted with students. Results The aggregation of results from the baseline experiment and two replications corroborates the following findings. There is a positive relationship between all four climate factors and satisfaction in software development teams. Teams whose members score highest for the agreeableness personality factor have the highest satisfaction levels. The results unveil a significant positive correlation between the extraversion personality factor and software product quality. High participative safety and task orientation climate perceptions are significantly related to quality. Conclusions First, more efficient software development teams can be formed heeding personality factors like agreeableness and extraversion. Second, the team climate generated in software development teams should be monitored for team member satisfaction. Finally, aspects like people feeling safe giving their opinions or encouraging team members to work hard at their job can have an impact on software quality. Software project managers can take advantage of these factors to promote developer satisfaction and improve the resulting product.This research has been funded by the following projects: Experiment Replication and Synthesis Technologies in SE (MICINN TIN2011-23216) and Go Lite (MICINN TIN2011-24139)

An Overabundance of Transient X-ray Binaries within 1 pc of the Galactic Center

During five years of Chandra observations, we have identified seven X-ray transients located within 23 pc of Sgr A*. These sources each vary in luminosity by more than a factor of 10, and have peak X-ray luminosities greater than 5e33 erg/s, which strongly suggests that they are accreting black holes or neutron stars. The peak luminosities of the transients are intermediate between those typically considered outburst and quiescence for X-ray binaries. Remarkably four of these transients lie within only 1 pc of Sgr A*. This implies that, compared to the numbers of similar systems located between 1 and 23 pc, transients are over-abundant by a factor of 20 per unit stellar mass within 1 pc of Sgr A*. It is likely that the excess transient X-ray sources are low-mass X-ray binaries that were produced, as in the cores of globular clusters, by three-body interactions between binary star systems and either black holes or neutron stars that have been concentrated in the central parsec through dynamical friction. Alternatively, they could be high-mass X-ray binaries that formed among the young stars that are present in the central parsec.Comment: 4 pages, including 2 figures (one color). Submitted to ApJ Letter

Flammability limits, ignition energy, and flame speeds in H₂–CH₄–NH₃–N₂O–O₂–N₂ mixtures

Experiments on flammability limits, ignition energies, and flame speeds were carried out in a 11.25- and a 400-liter combustion vessel at initial pressures and temperatures of 100 kPa and 295 K, respectively. Flammability maps of hydrogen–nitrous oxide–nitrogen, methane–nitrous oxide–nitrogen, ammonia–nitrous oxide–nitrogen, and ammonia–nitrous oxide–air, as well as lean flammability limits of various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures were determined. Ignition energy bounds of methane–nitrous oxide, ammonia–nitrous oxide, and ammonia–nitrous oxide–nitrogen mixtures have been determined and the influence of small amounts of oxygen on the flammability of methane–nitrous oxide–nitrogen mixtures has been investigated. Flame speeds have been measured and laminar burning velocities have been determined for ammonia–air–nitrous oxide and various hydrogen–methane–ammonia–nitrous oxide–oxygen–nitrogen mixtures. Lower and upper flammability limits (mixing fan on, turbulent conditions) for ignition energies of 8 J are: H₂–N₂O: 4.5 ∼ 5.0% H₂(LFL), 76 ∼ 80% H₂(UFL); CH₄–N₂O: 2.5 ∼ 3.0% CH₄(LFL), 43 ∼ 50% CH₄(UFL); NH₃–N₂O: 5.0 ∼ 5.2% NH₃(LFL), 67.5 ∼ 68% NH₃(UFL). Inerting concentrations are: H₂–N₂O–N₂: 76% N₂; CH₄–N₂O–N₂: 70.5% N₂; NH₃–N₂O–N₂: 61% N₂; NH₃–N₂O–air: 85% air. Flammability limits of methane–nitrous oxide–nitrogen mixtures show no pronounced dependence on small amounts of oxygen (<5%). Generally speaking, flammable gases with large initial amounts of nitrous oxide or ammonia show a strong dependence of flammability limits on ignition energy